The invention provides a process for recovering germanium as germanium oxide from a germaniferous metallic zinc which involves distilling the germaniferous metallic zinc under non-oxidizing conditions, recovering the distillation residue which contains the germanium, leaching the recovered distillation residue with chlorine water to convert the germanium into
Sep 18, 2018 Germanium is produced almost exclusively from waste residue of hydrometallurgical zinc processing operations (Llewellyn, 1989). Currently, high-grade domestic zinc residues containing enough germanium to supply the annual needs of the U.S. are processed in foreign countries by proprietary techniques to recover the germanium (Plunkert,
Recovery of germanium from Zn ore processing. ... Process for recovery of gallium and germanium from zinc resi-dues. Transactions of the Institution of
Zinc Co. in Clarksville, Tennessee produces germanium-rich residues by processing zinc ores from the nearby Elmwood- Gordonville mines. Most of these germanium-rich residues are shipped to Belgium for recovery and refining (U.S. Bu- reau of Mines, 1995). Germanium metal is presently valued at $482/pound(U.S. Bureau of Mines, 1995).
Jun 05, 2018 Zinc residue with high germanium, a waste solid product of hydrometallurgical zinc process is dumped continuously, causing the loss of germanium. Zinc residue was characterized by chemical analysis, X-ray diffraction, and inductively coupled plasma mass spectrometry methods. The results showed that, the mineralogical compositions of the zinc
Dec 29, 2013 Based on a detailed statistical analysis of chemical data published in the scientific literature, estimates were made of the minimum amounts of recoverable Ge contained within sulphidic zinc ores and coals, given current processing technologies. It is expected that at least 119 kt (7 kt in zinc ores and 112 kt in coal) of recoverable germanium exist within proven
Germanium is generally recovered through pyro-and hydro-metallurgical bulk ore processing (Moskalyk 2004). In some lead, zinc, and copper deposits, small (100 m) accessory Ge minerals that can ...
Sep 09, 2015 Germanium is present in soil around the world, but its difficult to extract and instead is often recovered as a byproduct of zinc ore
Techno-economic assessment of the process for recovery of indium, germanium and tin from alloys obtained as byproducts of zinc production Iris Winberg Masters thesis work supervised by D.Sc. Petteri Kangas, VTT Prof. Anders Brink, bo Akademi University Process Design and Systems Engineering Faculty of Science and Engineering
Jun 23, 2020 Currently, germanium is produced as a byproduct of zinc-bearing ore deposits. Acid mine drainage may have elevated signatures of germanium because of germaniums strong association to sulfide minerals (Shanks and others, 2017). Germanium is also recovered from lignite and coal deposits worldwide (Melcher and Buchholz, 2014).
The primary source of germanium around the world today is germanium that is produced as a by product of zinc refining 23. Germanium can be recovered from zinc bearing ores through many different methods including precipitation, cementation, solvent extraction, and ion exchange.
The element is commercially obtained from the dust from smelters that process zinc ores. It is also recovered from combustion by-products of certain coals. Germanium can be separated from other metals by fractional distillation of its volatile tetrachloride. These techniques permit the production of germanium of ultra-high purity. Properties
A zinc smelter in Clarksville, TN, produced and exported germanium leach concentrates recovered from processing zinc concentrates from the Middle Tennessee Mines. compounds and metal was imported into the United States for further processing by industry.
traditional roast-leach-electrowinning process of zinc hydrometallurgy, Ga and Ge can only be retrieved from these zinc sulfide concentrates with low rates of recovery and significantly high costs. Development of oxygen pressure leaching provides a more efficient way to extract germanium and gallium from a zinc sulfide concentrate.
Apr 27, 2007 Gallium is conventionally obtained as a byproduct of aluminum, and germanium as byproduct of zinc processing. An exception to this rule is the Apex Mine ore which has served as the only primary source in the world for direct production of gallium and germanium. In addition, the solvent extraction and bioleaching possibilities of these metals ...
The element is commercially obtained from the dusts of smelters processing zinc ores, as well as recovered from combustion by-products of certain coals. A large reserve of the elements for future uses in insured in coal sources. Germanium can be separated from other metals by fractional distillation of its volatile tetrachloride.
Dec 27, 2013 After mining, the ores are processed to increase their base metal and germanium contents using conventional mechanical and flotation methods. Future germanium supplies will continue to depend upon the availability of germaniumbearing residues from the processing of zinc ores, from germaniumbearing coal ash and from recycling.
Oct 09, 2019 Its also a byproduct of coal combustion and zinc ore processing. Germanium comes in two forms organic and inorganic. Both are sold as supplements. Organic germanium is a man-made blend of ...
Feb 01, 1993 Previous studies at the US Bureau of Mines (USBM) have shown that only 70% to 80% of the germanium in domestic zinc process residues can be extracted during H2SO4 leaching. To increase germanium extraction, the USBM developed and researched the hypothesis that minor amounts of germanium and zinc silicate, present in zinc calcine,
Germaniums abundance in the Earths crust is approximately 1.6 ppm. Only a few minerals like argyrodite, briartite, germanite, and renierite contain appreciable amounts of germanium, but none are in mineable deposits. Germanium seldom appears in high concentrations. It is mainly a byproduct of zinc ore processing.
Germanium is obtained commercially from zinc ore processing smelter dust and from the combustion by-products of certain coals. A large reserve of this element is therefore in coal sources. A large reserve of this element is therefore in coal sources.
Germanium is mainly a byproduct of zinc ore processing. It is a hard, grayish-white element it has a metallic luster and the same crystal structure as diamond and it is brittle, like glass. In addition, it is important to note that germanium is a semiconductor, with electrical properties between those of a metal and an insulator.
residues from the processing of zinc ores, coal ash, and from recycling. In recent years, exploration for new zinc deposits and expansions of known zinc mines have been maintained at a high level. Although information about germanium grades of discovered zinc deposits
Sep 01, 2016 The gallium and germanium in the zinc refinery residue mainly exist as dissociative or combined oxides that correlate with iron and silica. (2) The leaching of both gallium and germanium increase with increasing sulfuric acid concentration up to 156 g L 1 with ratios of 90.83% and 65.06%, respectively. Further increases in the sulfuric acid
Feb 08, 2018 The element is commercially obtained from the dusts of smelters processing zinc ores, as well as recovered from combustion by-products of certain coals. A large reserve of the elements for future uses in insured in coal sources. Germanium can be separated from other metals by fractional distillation of its volatile tetrachloride.
Germanium seldom appears in high concentrations. It is mainly a byproduct of zinc ore processing. The importance of recycled germanium recovered from end-of-life products, such as fiber optics, military vehicles, and solar cells, should not be underestimated.
The few minerals in which germanium exists as a main component (argyrodite, briartite, germanite, renierite and stottite) are extremely rare and do not form rich ore deposits. Therefore, germanium is mainly produced as a by-product of the zinc processing industry.
Jun 25, 2019 Germanium is most commonly produced from sphalerite zinc ores but is also known to be extracted from fly ash coal (produced from coal power plants) and some copper ores. Regardless of the source of material, all germanium concentrates are first purified using a chlorination and distillation process that produces germanium tetrachloride (GeCl4).
Germanium-bearing concentrates are processed at our integrated lead/zinc refinery in Trail. We produce a wide offering of high quality germanium products, many of which have been developed in conjunction with our customers. Teck maintains a Quality Management System for Germanium Products that complies with the requirements of ISO 90012015.
Zinc ore occurs in two types of deposit as primary zinc ore in thin veins known as rakes, or a secondary deposit formed by weathering of the primary mineral veins. Zinc ore is most commonly found as zinc carbonate (ZnCO 3), known as calamine or smithsonite. It generally occurs as rounded, crystalline crusts or granular, honeycombed masses that ...
Jan 23, 2020 Germanium is found in argyrodite (a sulfide of germanium and silver), in germanite (composed of about 8% of the element), in coal, in zinc ores, and other minerals. The element may be commercially prepared from the flue dust of smelters processing zinc ores or from the by-products of the combustion of certain coals.
Germanium. Germanium is extracted from germanium bearing zinc ores or from certain coal ores, collecting the flue dusts after the burning process. It can occasionally be found in copper ores. We refine germanium at our facility in the USA.
Germanium minerals are also present in zinc ores, and commercial production of germanium is carried out by processing zinc smelter flue dust. It can also be recovered from the by-products of combustion of certain coals. Applications of Germanium. Germanium is a semiconductor.
Apr 29, 2020 Currently, germanium is produced as a byproduct of zinc-bearing ore deposits. Acid mine drainage may have elevated signatures of germanium because of germaniums strong association to sulfide minerals (Shanks and others, 2017). Germanium is also recovered from lignite and coal deposits worldwide (Melcher and Buchholz, 2014).